United are compiling their list of summer targets with Louis van Gaal set to be handed up to £150million to splurge on new recruits.
Right-back has proved to be a problematic position for Van Gaal, and Rafael could leave Old Trafford.
Clyne is on Van Gaal's radar, and their chances of signing him have been given a timely boost according to Spanish paper Marca, who claim Alves will join PSG.
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Manchester United are keen on signing Nathaniel Clyne
It is suggested Alves will put pen to paper on a three-year deal at the Parc des Princes.
Alves is thought to have verbally agreed the deal on Tuesday and will link up with his international team-mates David Luiz, Marquinhos, Thiago Silva and Maxwell.
Manchester United have also been tracking Borussia Dortmund centre half Mats Hummels.
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