The Blues grabbed a 1-1 draw in the first leg of the last 16 clash at the Parc des Princes, and will be hoping they can do enough at Stamford Bridge to secure a place in the quarter finals.
And speaking ahead of kick-off, Mourinho revealed that Chelsea won't be on the defensive against the likes of Edinson Cavani and Zlatan Ibrahimovic.
He said: "1-1 away from home, if you are playing a team who is clearly inferior to your team is a great result and you are in control.
Mourinho on PSG and Cesc Fabregas [AMBIENT]
To go and defend and wait for things to happen is not the right approach
Jose Mourinho
"1-1 away with a team who has power, has experience, has ambition, has pressure to succeed, it is a very dangerous result. Both teams are at the limit, this is the last-16 match with the two best teams against each other.
"A big team will be out in a couple of hours and we know that it is a big game in front of us.
"It will be 90 minutes against a team with fantastic players in attack but to go and defend and wait for things to happen is not the right approach.
"Even scoring before them everything will still be open because the result is so tight but we will start in a strong way."
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